So far the silicone is still working. Pull the pads and clean the back side of them. Apply a thin coat of high temp silicone in a circle shape where the piston meets the pad. Carefully re-insert the pad trying not to rub the silicone off. Once in position, apply the brake to stick them together. Now let it set a few hours for the silicone to set up.
So you are using RTV and gluing the pads to the pistons? If so I am thinking it is not a good idea.
I thought you were using a silicone grease of some type.
Every tire change I clean calipers and brake pads, including pistons. I also use anti seize on any anti rattle clip or retaining pins, I also use a very fine coat to the back of the pad area you are describing to keep the pistons and the pads all moving freely with a bit of high temp anti seize. I was taught this many many years ago and I have never had any issues with brakes other then loose rotor buttons on the K1200 LT, which they replaced after some fussing.
I have heard of disk break pad spray you sprayed on the back of the pads but it looked like a thick smooth "rubberized" coating but it's intent was to deaden sound and the pistons did not stick to it.
I would worry of RTV coming loose and ending up in the piston path and be forced into the seal and cause a leak. Or burning it on my pads if it came loose.
Just me and I am sure I am too fussy.