Check this out:
<a href="
https://blogs.consumerreports.org/cars/2007/10/tires-nitrogen-.html" target="_blank">
https://blogs.consumerreports.org/cars/2007...-nitrogen-.html</a>
probably not worth the extra $$
I just did some quick math and figured this out. (Assuming that the oxygen is preferentially leaking from the tire)
1) fill tire with air = 78% Nitrogen, 21% O2, 1% other stuff
2) allow all Oxygen to "leak" out = -21% gas loss, tire now contains nearly pure nitrogen (at a lowered pressure)
3) refill with air again = 95% nitrogen in tire
Essentially, if oxygen is the primary cause of pressure loss, then each time you pump them back up, the N2 concentration increases.