No, the octane rating of gasoline is based solely on at what pressure (temperature) it will auto ignite. It is not a direct measurement of density.
As mentioned previously, using higher octane fuels is useful in engines designed with higher compression ratios or those with forced induction that pre-compress the intake charge resulting in a higher effective compression, to prevent the detonation or pre-ignition (knocking) which can be mechanically detrimental to the engine's longevity. When used with these higher compression ratios that modified engine will produce more power, not because the high octane fuel contains more power, but because the engine will extract more of the available power content from the fuel via the higher compression (not to mention that you can cram more fuel air mixture in per stroke).
The burn rate of various octane rated fuels is the same once ignited (via spark). No (additional) raw fuel will be ejected in the exhaust stream by using too high an octane (a common fallacy). THe fuel will burn to the same degree and no added carbon deposits will be produced. The caloric values and densities of these fuels is the same for all intents. The fuels will perform nearly identically with the main difference being that the higher octane rated fuel will not spontaneously combust as early in high compression situations. So, on a relatively low compression engine using a higher octane fuel (with all other things remaining equal) will not affect your gas mileage significantly for the better or worse.
In the past, premium gasolines would often have more detergents added in order to help justify the increased prices. In modern times, most fuel companies will now admit that they use the exact same detergent packages in all grades of fuel and only alter the formulas between grades to produce the higher octane rating.
That doesn't mean that fuel is composed that way, that is just how the scale was composed. (IOW 93 octane rated gasoline is not 93% iso-octane and 7% heptane) The actual additives to the base gasoline that produce the higher octane rating will insignificantly lessen the fuel density, not by very much. The caloric value of the fuel will be slightly less due to that same factor. Warmer fuel will also have a lower density and will have a similar (negligible) effect.The octane rating of gasoline is measured in a test engine and is defined by comparison with the mixture of 2,2,4-trimethylpentane (iso-octane) and heptane that would have the same anti-knocking capacity as the fuel under test: the percentage, by volume, of 2,2,4-trimethylpentane in that mixture is the octane number of the fuel.
As mentioned previously, using higher octane fuels is useful in engines designed with higher compression ratios or those with forced induction that pre-compress the intake charge resulting in a higher effective compression, to prevent the detonation or pre-ignition (knocking) which can be mechanically detrimental to the engine's longevity. When used with these higher compression ratios that modified engine will produce more power, not because the high octane fuel contains more power, but because the engine will extract more of the available power content from the fuel via the higher compression (not to mention that you can cram more fuel air mixture in per stroke).
The burn rate of various octane rated fuels is the same once ignited (via spark). No (additional) raw fuel will be ejected in the exhaust stream by using too high an octane (a common fallacy). THe fuel will burn to the same degree and no added carbon deposits will be produced. The caloric values and densities of these fuels is the same for all intents. The fuels will perform nearly identically with the main difference being that the higher octane rated fuel will not spontaneously combust as early in high compression situations. So, on a relatively low compression engine using a higher octane fuel (with all other things remaining equal) will not affect your gas mileage significantly for the better or worse.
In the past, premium gasolines would often have more detergents added in order to help justify the increased prices. In modern times, most fuel companies will now admit that they use the exact same detergent packages in all grades of fuel and only alter the formulas between grades to produce the higher octane rating.
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